Os químicos desenvolvem uma variedade de processos sintanãticos industrialmente importantes
Um desses processos, a meta¡tese da olefina, recebeu atenção especial nas últimas décadas e o Praªmio Nobel de Química de 2005 foi concedido em reconhecimento a sua importa¢ncia.
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)
Prof. Dr. David Scheschkewitz Crédito: Saarland University / Oliver Dietze
A formação de ligações duplas entre dois a¡tomos de carbono (C = C) éde importa¢ncia central em organismos naturais. A grande maioria das substâncias naturais, portanto, contanãm uma ou mais dessas ligações duplas. Os compostos com ligações duplas C = C, os alcenos ou olefinas, também desempenham um papel proeminente na indústria química orga¢nica. Muitos processos quamicos, portanto, foram desenvolvidos ao longo dos anos para controlar a formação de ligações C = C.
Um desses processos, a meta¡tese da olefina, recebeu atenção especial nas últimas décadas e o Praªmio Nobel de Química de 2005 foi concedido em reconhecimento a sua importa¢ncia.
Apesar dos muitos paralelos entre o carbono e os membros mais pesados ​​do grupo de carbono (Grupo 14) da tabela peria³dica , a meta¡tese de olefinas são teve significado prático quando os compostos contendo ligações C = C estavam envolvidos. Isso parece um tanto surpreendente, dado o fato de que as ligações duplas entre os elementos mais pesados ​​do grupo de carbono são consideravelmente mais fracas do que uma ligação C = C e, portanto, são mais facilmente clivadas.
David Scheschkewitz, Professor de Química Inorga¢nica e Geral da Saarland University, Lukas Klemmer e Anna-Lena Tha¶mmes de seu grupo de pesquisa e Volker Huch e Bernd Morgenstern do Centro de Difração de Raios-X desenvolveram e caracterizaram uma nova classe de produtos mais pesados ​​a base de germa¢nio ana¡logos de alceno cuja ligação Ge = Ge exibe o grau certo de estabilidade para participar de reações de meta¡tese sinteticamente aºteis.
O grupo Scheschkewitz empregou a nova metodologia para sintetizar os primeiros polímeros de cadeia longa contendo ligações duplas entre elementos mais pesados. Em um futuro pra³ximo, os pesquisadores esperam estender o conceito a outros elementos da tabela peria³dica, que podem ser de uso potencial no desenvolvimento de novos materiais para aplicações no campo da eletra´nica orga¢nica. “O princapio subjacente ésimples e também pode ser aplicado na química orga¢nicaâ€, explica o professor Scheschkewitz.
Potencialmente, isso também poderia fornecer um meio de realizar reações de meta¡tese de olefinas sem os catalisadores de metais preciosos necessa¡rios na abordagem tradicional.